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Author(s):   Andersen, M.PS.; Nielsen, O.J.; Toft, A.; Nakayama, T.; Matsumi, Y.; Waterland, R.L.; Buck, R.C.; Hurley, M.D.; Wallington, T.J.
Title:   Atmospheric chemistry of CxF2x+1CH=CH2 (x=1, 2, 4, 6, and 8): Kinetics of gas-phase reactions with Cl atoms, OH radicals, and O3
Journal:   AIAA J.
Volume:   176
Page(s):   124 - 128
Year:   2005
Reference type:   Journal article
Squib:   2005AND/NIE124-128

Reaction:   C8F17CH=CH2 + ·Cl → Products
Reaction order:   2
Reference reaction:   C2H2 + ·Cl → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   1.77±1.4x10-1
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   There was no effect of size on the measured rate constants for a series of CxF2x+1CH=CH2 reactions, so an average value for the entire set was reported.
Bothe nitrogen and air used as bath gas, with no apparant difference.

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