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Accessibility information
Author(s):   Brand, U.; Hippler, H.; Lindemann, L.; Troe, J.
Title:   C-C and C-H bond splits of laser-excited aromatic molecules. 1. Specific and thermally averaged rate constants
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   6305 - 6316
Year:   1990
Reference type:   Journal article
Squib:   1990BRA/HIP6305-6316

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1990BRA/HIP6305-6316   1,2-Dimethylbenzene2-Methylbenzyl +   1100 - 1900   1.10E16       3.73E05      1
  1990BRA/HIP6305-6316   t-Butylbenzene·CH3 + 2-Phenyl-2-propyl radical  900 - 1700   1.58E16       2.86E05      1
  1990BRA/HIP6305-6316   2-Phenylpropane·CH3 + 1-phenylethyl  900 - 1700   6.31E15       2.98E05      1
  1990BRA/HIP6305-6316   EthylbenzeneBenzyl + ·CH3  900 - 1700   2.09E16       3.23E05      1
  1990BRA/HIP6305-6316   1,4-Dimethylbenzene4-Methylbenzyl +   1100 - 1900   1.78E16       3.69E05      1
  1990BRA/HIP6305-6316   1,3-Dimethylbenzene3-Methylbenzyl +   1100 - 1900   1.95E16       3.71E05      1
  1990BRA/HIP6305-6316   1,3,5-Trimethylbenzene + Methyl,(3,5-dimethylphenyl)-  1100 - 1900   2.24E16       3.65E05      1
  1990BRA/HIP6305-6316   TolueneBenzyl +   300 - 1200   1.82E16       3.84E05      1
  1990BRA/HIP6305-6316   Benzyl + ·CH3Ethylbenzene  300 - 1900   1.98E-11       923      2
  1990BRA/HIP6305-6316   Benzyl + Toluene  300 - 1100   3.45E-10       358      2
  1990BRA/HIP6305-6316   ·CH3 + 1-phenylethyl2-Phenylpropane  300 - 1900   2.87E-11       898      2
  1990BRA/HIP6305-6316   ·CH3 + 2-Phenyl-2-propyl radicalt-Butylbenzene  300 - 1700   1.19E-11       141      2
  1990BRA/HIP6305-6316   3-Methylbenzyl + 1,3-Dimethylbenzene  300 - 1900   2.54E-10       615      2
  1990BRA/HIP6305-6316   2-Methylbenzyl + 1,2-Dimethylbenzene  300 - 1900   1.24E-10       324      2
  1990BRA/HIP6305-6316   4-Methylbenzyl + 1,4-Dimethylbenzene  300 - 1900   4.15E-10       698      2
  1990BRA/HIP6305-6316   + Methyl,(3,5-dimethylphenyl)- → 1,3,5-Trimethylbenzene  300 - 1900   1.30E-10       582      2

Search returned 16 records.