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Accessibility information
Author(s):   Davidson, I.M.T.; Ring, M.A.
Title:   Primary processes in the low-pressure pyrolysis of methylsilane
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   76
Page(s):   1520 - 1525
Year:   1980
Reference type:   Journal article
Squib:   1980DAV/RIN1520-1525

Reaction:   CH3SiH3CH4 + SiH2
Reaction order:   1
Temperature:   842 - 1000 K
Rate expression:   3.98x1013 [s-1] e-299321 [±8980 J/mole]/RT
Bath gas:   CH3SiH3
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
842 1.08E-5
850 1.61E-5
875 5.39E-5
900 1.69E-4
925 4.98E-4
950 1.39E-3
975 3.67E-3
1000 9.23E-3