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Accessibility information
Author(s):   Dixon, P.S.; Szwarc, M.
Title:   Reactions of CF3 radicals in the gaseous and liquid phases. Effect of solvent upon the rate constants
Journal:   Trans. Faraday Soc.
Volume:   59
Page(s):   112 - 117
Year:   1963
Reference type:   Journal article
Squib:   1963DIX/SZW112-117

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1963DIX/SZW112-117   Benzene + ·CF3 → Adduct  338   0.82              2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2 2
  1963DIX/SZW112-117   CH2=CHCl + ·CF3 → Adduct  338   36.80              2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2 2
  1963DIX/SZW112-117   CH2=CHF + ·CF3 → Adduct  338   7.00              2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2 2
  1963DIX/SZW112-117   1,3-Butadiene + ·CF3 → Adduct  338   782              2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2 2
  1963DIX/SZW112-117   CH3CH=CH2 + ·CF3 → Adduct  338   92.90              2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2 2
  1963DIX/SZW112-117   iso-C4H8 + ·CF3 → Adduct  338   278              2
  Reference reaction:  (CH3)3CCH2CH3 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2 2
  1963DIX/SZW112-117   Cyclopentene + ·CF3 → Adduct  338   49.80              2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2 2
  1963DIX/SZW112-117   (CH3)2C=C(CH3)2 + ·CF3 → Adduct  338   101              2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2 2
  1963DIX/SZW112-117   CH3CF=CH2 + ·CF3 → Adduct  338   31.70              2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2 2

Search returned 9 records.