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Accessibility information
Author(s):   Tedder, J.M.; Walton, J.C.
Title:   Free radical addition to olefins. Part 3.-Addition of trichloromethyl radicals to propene, 2-fluoropropene and hexafluoropropene
Journal:   Trans. Faraday Soc.
Volume:   63
Page(s):  
Year:   1967
Reference type:   Journal article
Squib:   1967TED/WAL2678

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1967TED/WAL2678   CH3CH=CH2 + ·CCl3CHCl3 + ·CH2CH=CH2  332 - 483   1.66E-12       2.64E04      2
  1967TED/WAL2678   CH3CH=CH2 + ·CCl3 → CCl3CH2CHCH3  332 - 483   2.62E-14       1.42E04      2
  1967TED/WAL2678   CF3CF=CF2 + ·CCl3 → CCl3CF2CF(·)CF3  332 - 483   5.25E-15       2.59E04      2
  1967TED/WAL2678   CH3CF=CH2 + ·CCl3 → CCl3CH2CF(·)CH3  332 - 483   1.05E-14       1.34E04      2
  1967TED/WAL2678   CH3CF=CH2 + ·CCl3 → CH3CF(CCl3)CH2·  332 - 483   4.17E-14       2.68E04      2
  1967TED/WAL2678   CH3CF=CH2 + ·CCl3 → ·CH2CF=CH2 + CHCl3  332 - 483   1.66E-12       2.76E04      2

Search returned 6 records.