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Accessibility information
Author(s):   Lloyd, A.C.
Title:   Evaluated and estimated kinetic data for phase reactions of the hydroperoxyl radical
Journal:   Int. J. Chem. Kinet.
Volume:   6
Page(s):   169 - 228
Year:   1974
Reference type:   Journal article
Squib:   1974LLO169-228

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1974LLO169-228   CH2O + HO2HCO + H2O2  300 - 800   1.66E-12       3.34E04      2
  1974LLO169-228   C2H6 + HO2·C2H5 + H2O2  300 - 1000   1.66E-12       5.85E04      2
  1974LLO169-228   C2H4 + HO2 → Products  300   1.66E-17              2
  1974LLO169-228   C3H8 + HO2iso-C3H7 + H2O2  300 - 1000   3.32E-13       4.39E04      2
  1974LLO169-228   iso-C4H10 + HO2tert-C4H9 + H2O2  300 - 1000   1.66E-13       2.93E04      2
  1974LLO169-228   n-C4H10 + HO2sec-C4H9 + H2O2  300 - 1000   8.30E-13       4.39E04      2
  1974LLO169-228   iso-C4H8 + HO2 → Products  300   1.66E-16              2
  1974LLO169-228   CO + HO2CO2 + ·OH  300 - 1000   1.66E-13       4.18E04      2
  1974LLO169-228   H2 + HO2H2O2 +   300 - 1000   1.21E-12       7.82E04      2
  1974LLO169-228   HO2O2 +   300 - 2000   3.49E-09       1.92E05      2
  1974LLO169-228   HO2 + HO2H2O2 + O2  300 - 1000   1.66E-11       4182      2
  1974LLO169-228   HO2 + ·OHH2O + O2  300 - 1000   8.30E-11       4182      2
  1974LLO169-228   HO2 + SO2·OH + SO3  300   8.63E-16              2
  1974LLO169-228   HO2 + H2O·OH + H2O2  300 - 1000   4.65E-11       1.37E05      2
  1974LLO169-228   HO2 + O3·OH + O2 + O2  200 - 500   1.66E-13       1.17E04   1.46E-15  2
  1974LLO169-228   HO2 + Br·O2 + HBr  300 - 1000   1.66E-11       2087      2
  1974LLO169-228   HO2 + H2 + O2  300 - 1000   4.15E-11       2927      2
  1974LLO169-228   HO2 + ·OH + ·OH  300 - 1000   4.15E-10       7949      2
  1974LLO169-228   HO2 + H2O +   300 - 1000   8.30E-11       4182      2
  1974LLO169-228   HO2 + ·OH + O2  298 - 302   8.30E-11       4182   1.54E-11  2
  1974LLO169-228   HOONO·OH + NO2  300   1.00E11              1

Search returned 21 records.