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Accessibility information
Author(s):   Ellis, C.; Scott, M.S.; Walker, R.W.
Title:   Addition of toluene and ethylbenzene to mixture of H2 and O2 at 772 K: Part 2: Formation of products and determination of kinetic data for H plus additive and for other elementary reactions involved
Journal:   Combust. Flame
Volume:   132
Page(s):   291 - 304
Year:   2003
Reference type:   Journal article
Squib:   2003ELL/SCO291-304

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2003ELL/SCO291-304   Benzyl + HO2·OH + C6H5CH2O  773   8.47E-12              2
  2003ELL/SCO291-304   C6H5CH2OO → C6H5CH(·)OOH  773   2800              1
  2003ELL/SCO291-304   1-phenylethyl + HO2 → C6H5CH(OOH)CH3  773   1.21E-11              2
  2003ELL/SCO291-304   Benzyl + HO2·OH + C6H5CH2O  500 - 1500   8.30E-12              2
  2003ELL/SCO291-304   Toluene + H2 + Benzyl  773   3.65E-13              2
  2003ELL/SCO291-304   Toluene + H2 + Benzyl  500 - 1500   7.37E-12   2.00   3.18E04      2
  2003ELL/SCO291-304   Toluene + → C6H4CH3 + H2  773   3.16E-14              2
  2003ELL/SCO291-304   Toluene + → C6H4CH3 + H2  500 - 1500   2.80E-12   2.00   4.06E04      2
  2003ELL/SCO291-304   Toluene + Benzene + ·CH3  773   4.32E-13              2
  2003ELL/SCO291-304   Toluene + Benzene + ·CH3  500 - 1500   1.40E-13   2.00   3949      2
  2003ELL/SCO291-304   Toluene + → Products  773   8.30E-13              2
  2003ELL/SCO291-304   Toluene + → Products  500 - 1500   2.71E-15   5.20   -5612      2
  2003ELL/SCO291-304   Ethylbenzene + H2 + 1-phenylethyl  773   1.01E-12              2
  2003ELL/SCO291-304   Ethylbenzene + H2 + 1-phenylethyl  500 - 1500   4.87E-12   2.00   2.24E04      2
  2003ELL/SCO291-304   Ethylbenzene + H2 + 2-phenylethyl  773   2.08E-13              2
  2003ELL/SCO291-304   Ethylbenzene + H2 + 2-phenylethyl  500 - 1500   6.15E-12   1.50   3.10E04      2
  2003ELL/SCO291-304   Ethylbenzene + → C6H4CH2CH3 + H2  773   3.16E-14              2
  2003ELL/SCO291-304   Ethylbenzene + → C6H4CH2CH3 + H2  500 - 1500   2.80E-12   2.00   4.06E04      2
  2003ELL/SCO291-304   Ethylbenzene + Benzene + ·C2H5  773   5.15E-13              2
  2003ELL/SCO291-304   Ethylbenzene + Benzene + ·C2H5  500 - 1500   1.47E-13   2.00   3949      2
  2003ELL/SCO291-304   Ethylbenzene + → Products  773   1.78E-12              2
  2003ELL/SCO291-304   Ethylbenzene + → Products  500 - 1500   6.72E-13   3.00   1.31E05      2
  2003ELL/SCO291-304   Toluene + H2 + Benzyl  773   34.00              2
  Reference reaction:  O2 + ·OH + 2
  2003ELL/SCO291-304   Toluene + → C6H4CH3 + H2  773   3.00              2
  Reference reaction:  O2 + ·OH + 2
  2003ELL/SCO291-304   Toluene + Benzene + ·CH3  773   41.00              2
  Reference reaction:  O2 + ·OH + 2
  2003ELL/SCO291-304   Toluene + → Products  773   78.00              2
  Reference reaction:  O2 + ·OH + 2
  2003ELL/SCO291-304   Ethylbenzene + H2 + 1-phenylethyl  773   96.00              2
  Reference reaction:  O2 + ·OH + 2
  2003ELL/SCO291-304   Ethylbenzene + H2 + 2-phenylethyl  773   19.50              2
  Reference reaction:  O2 + ·OH + 2
  2003ELL/SCO291-304   Ethylbenzene + → C6H4CH2CH3 + H2  773   3.00              2
  Reference reaction:  O2 + ·OH + 2
  2003ELL/SCO291-304   Ethylbenzene + Benzene + ·C2H5  773   8.14E-20              2
  Reference reaction:  O2 + ·OH + 2
  2003ELL/SCO291-304   Ethylbenzene + → Products  773   2.79E-19              2
  Reference reaction:  O2 + ·OH + 2

Search returned 31 records.