Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Seta, T.; Nakajima, M.; Miyoshi, A.
Title:   High-temperature reactions of OH radicals with benzene and toluene
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   5081 - 5090
Year:   2006
Reference type:   Journal article
Squib:   2006SET/NAK5081-5090

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2006SET/NAK5081-5090   Benzene + ·OH → Products  908 - 1736   8.00E-11       2.66E04      2
  2006SET/NAK5081-5090   Toluene + ·OH → Products  919 - 1481   8.90E-11       1.97E04      2
  2006SET/NAK5081-5090   Benzene + ·OH → Products  700 - 1900   1.14E-13   2.91   1921      2
  2006SET/NAK5081-5090   Benzene + ·OHPhenyl + H2O  700 - 1900   1.69E-13   2.68   3068      2
  2006SET/NAK5081-5090   Benzene + ·OHPhenol +   700 - 1900   2.41E-14   3.25   2.34E04      2
  2006SET/NAK5081-5090   Toluene + ·OH → Products  700 - 1900   1.89E-13   2.78   -3367      2
  2006SET/NAK5081-5090   Toluene + ·OHBenzyl + H2O  700 - 1900   2.46E-13   2.39   -2519      2
  2006SET/NAK5081-5090   Toluene + ·OH → C6H4CH3 + H2O  700 - 1900   1.03E-13   2.69   2594      2
  2006SET/NAK5081-5090   Toluene + ·OHH2O + Phenyl, 2-methyl-  700 - 1900   2.47E-14   2.61   1297      2
  2006SET/NAK5081-5090   Toluene + ·OH → Phenyl, 3-methyl- + H2O  700 - 1900   5.60E-14   2.69   3858      2
  2006SET/NAK5081-5090   Toluene + ·OH → Phenyl, 4-methyl- + H2O  700 - 1900   2.89E-14   2.66   2536      2
  2006SET/NAK5081-5090   Toluene + ·OHPhenol + ·CH3  700 - 1900   1.78E-14   2.88   1.35E04      2
  2006SET/NAK5081-5090   Toluene + ·OH → methylphenol (unspecified isomer) +   700 - 1900   1.10E-14   3.36   1.97E04      2
  2006SET/NAK5081-5090   Toluene + ·OH2-Methylphenol +   700 - 1900   3.24E-15   3.26   1.72E04      2
  2006SET/NAK5081-5090   Toluene + ·OH3-Methylphenol +   700 - 1900   7.80E-15   3.24   2.22E04      2
  2006SET/NAK5081-5090   Toluene + ·OH4-Methylphenol +   700 - 1900   4.31E-15   3.23   2.41E04      2

Search returned 16 records.