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Accessibility information
Author(s):   Buback, M.; Kling, M.; Schmatz, S.
Title:   Decomposition of tertiary alkoxy radicals
Journal:   Z. Phys. Chem.
Volume:   219
Page(s):   1205 - 1222
Year:   2005
Reference type:   Journal article
Squib:   2005BUB/KLI1205-1222

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2005BUB/KLI1205-1222   (CH3)3CO· → (CH3)2CO + ·CH3  200 - 700   1.30E14       6.26E04   1385  1
  2005BUB/KLI1205-1222   (CH3)3CO-C3H8 complex → Propyl Radical + tert-C4H9OH  200 - 700   3.60E10       2.27E04   3.78E06  1
  2005BUB/KLI1205-1222   CH3CH2C(CH3)2O(·) → C2H5COCH3 + ·CH3  200 - 700   1.30E14       6.04E04   3365  1
  2005BUB/KLI1205-1222   CH3CH2C(CH3)2O(·) → (CH3)2CO + ·C2H5  200 - 700   1.10E14       4.57E04   1.07E06  1
  2005BUB/KLI1205-1222   C2H5(CH3)2CO-C3H8 complex → Propyl Radical + C2H5C(CH3)2OH  200 - 700   8.00E10       2.31E04   7.15E06  1
  2005BUB/KLI1205-1222   (CH3)3CC(CH3)2O· → tert-C4H9COCH3 + ·CH3  200 - 700   7.90E13       6.00E04   2403  1
  2005BUB/KLI1205-1222   (CH3)3CC(CH3)2O· → (CH3)2CO + tert-C4H9  200 - 700   1.10E14       2.08E04   2.49E10  1
  2005BUB/KLI1205-1222   (CH3)3CC(CH3)2O-C3H8 complex → Propyl Radical + (CH3)3CC(CH3)2OH  200 - 700   4.70E10       2.89E04   4.04E05  1
  2005BUB/KLI1205-1222   (CH3)3CCH2C(CH3)2O· → neo-C5H11COCH3 + ·CH3  200 - 700   5.60E13       5.53E04   1.14E04  1
  2005BUB/KLI1205-1222   (CH3)3CCH2C(CH3)2O· → (CH3)2CO + Neopentyl  200 - 700   4.60E13       3.56E04   2.65E07  1
  2005BUB/KLI1205-1222   (CH3)3CCH2C(CH3)2O· → C(CH2·)(CH3)2CH2C(CH3)2OH  200 - 700   2.90E12       3.35E04   3.89E06  1
  2005BUB/KLI1205-1222   (CH3)3CCH2C(CH3)2O-C3H8 complex → Propyl Radical + (CH3)3CCH2C(CH3)2OH  200 - 700   1.00E10       2.68E04   2.01E05  1

Search returned 12 records.