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Home ©NIST, 2013 Accessibility information |
Title: The homogeneous thermal polymerization of 1,3-butadiene
Journal: J. Am. Chem. Soc.
Volume: 54
Page(s): 3863 - 3876
Year: 1932
Reference type: Journal article
Squib: 1932VAU3863-3876
Reaction:
1,3-Butadiene + 1,3-Butadiene → 4-Vinylcyclohexene
Reaction order:
2
Temperature:
653 - 709
K
Pressure: 2.00E-3 - 0.96 bar
Rate expression:
7.82x10-14 [cm3/molecule s] e-108920 [J/mole]/RT
Bath gas:
1,3-Butadiene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 653 | 1.52E-22 |
| 675 | 2.92E-22 |
| 700 | 5.83E-22 |
| 709 | 7.39E-22 |