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Accessibility information
Author(s):   Kistiakowsky, G.B.; Van Artsdalen, E.R.
Title:   Bromination of hydrocarbons. I. Photochemical and thermal bromination of methane and methyl bromine. Carbon-hydrogen bond strength in methane
Journal:   J. Chem. Phys.
Volume:   12
Page(s):  
Year:   1944
Reference type:   Journal article
Squib:   1944KIS/VAN469

Reaction:   CH3Br + Br·HBr + ·CH2Br
Reaction order:   2
Reference reaction:   H2 + Br·HBr +
Reference reaction order:   2
Temperature:   423 - 483 K
Pressure:  0.33 - 0.51 bar
Rate expression:   1.25 e8564 [J/mole]/RT
Bath gas:   CH4
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
423 1.43E1
425 1.41E1
450 1.23E1
475 1.09E1
483 1.05E1