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Title: The kinetics of the dehydrochlorination of substituted hydrocarbons. Part II. The mechanism of the thermal decomposition of 1:2-dichloroethane
Journal: J. Chem. Soc.
Page(s): 155 - 164
Year: 1949
Reference type: Journal article
Squib: 1949BAR/HOW155-164
Reaction:
CH2ClCH2Cl → CH2=CHCl + HCl
Reaction order:
1
Temperature:
635 - 758
K
Pressure: 2.67E-2 - 0.27 bar
Rate expression:
6.4x1010 [s-1] e-197053 [J/mole]/RT
Bath gas:
CH2ClCH2Cl
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 635 | 3.95E-6 |
| 650 | 9.36E-6 |
| 675 | 3.61E-5 |
| 700 | 1.27E-4 |
| 725 | 4.07E-4 |
| 750 | 1.21E-3 |
| 758 | 1.69E-3 |