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Title: The thermal dimerization of butadiene, and the equilibrium between butadiene and vinylcyclohexene
Journal: J. Chem. Phys.
Volume: 20
Page(s): 1644 - 1645
Year: 1952
Reference type: Journal article
Squib: 1952DUN/JAN1644-1645
Reaction:
4-Vinylcyclohexene → 1,3-Butadiene + 1,3-Butadiene
Reaction order:
1
Temperature:
600 - 1000
K
Rate expression:
5.02x1015 [s-1] e-258580 [J/mole]/RT
Bath gas:
4-Vinylcyclohexene
Category: Experiment
Data type:
Derived from detailed balance/reverse rate
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 600 | 1.55E-7 |
| 625 | 1.23E-6 |
| 650 | 8.34E-6 |
| 675 | 4.91E-5 |
| 700 | 2.54E-4 |
| 725 | 1.18E-3 |
| 750 | 4.92E-3 |
| 775 | 1.87E-2 |
| 800 | 6.57E-2 |
| 825 | 2.13E-1 |
| 850 | 6.47E-1 |
| 875 | 1.84E0 |
| 900 | 4.94E0 |
| 925 | 1.26E1 |
| 950 | 3.04E1 |
| 975 | 7.04E1 |
| 1000 | 1.56E2 |