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Accessibility information
Author(s):   Duncan, N.E.; Janz, G.J.
Title:   The thermal dimerization of butadiene, and the equilibrium between butadiene and vinylcyclohexene
Journal:   J. Chem. Phys.
Volume:   20
Page(s):   1644 - 1645
Year:   1952
Reference type:   Journal article
Squib:   1952DUN/JAN1644-1645

Reaction:   4-Vinylcyclohexene1,3-Butadiene + 1,3-Butadiene
Reaction order:   1
Temperature:   600 - 1000 K
Rate expression:   5.02x1015 [s-1] e-258580 [J/mole]/RT
Bath gas:   4-Vinylcyclohexene
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
600 1.55E-7
625 1.23E-6
650 8.34E-6
675 4.91E-5
700 2.54E-4
725 1.18E-3
750 4.92E-3
775 1.87E-2
800 6.57E-2
825 2.13E-1
850 6.47E-1
875 1.84E0
900 4.94E0
925 1.26E1
950 3.04E1
975 7.04E1
1000 1.56E2