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Title: Reactions of free radicals with aldehydes. The reactions of methyl and t-butoxy radicals with acetaldehyde and acrolein
Journal: J. Chem. Phys.
Volume: 20
Page(s):
Year: 1952
Reference type: Journal article
Squib: 1952VOL/BRI1764
Reaction:
CH3CHO + ·CH3 → CH4 + CH3CO
Reaction order:
2
Reference reaction:
·CH3 + ·CH3 → C2H6
Temperature:
397 - 428
K
Pressure: 2.01E-2 - 0.32 bar
Rate expression:
1.2x10-12 [cm3/molecule s] (T/298 K)0.50 e-31346 [±1255 J/mole]/RT
Bath gas:
CH3CHO
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 397 | 1.04E-16 |
| 400 | 1.12E-16 |
| 425 | 2.02E-16 |
| 428 | 2.15E-16 |