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Accessibility information
Author(s):   Blades, A.T.
Title:   The kinetics of the pyrolysis of ethyl and isopropyl formates and acetates
Journal:   Can. J. Chem.
Volume:   32
Page(s):   366 - 372
Year:   1954
Reference type:   Journal article
Squib:   1954BLA366-372

Reaction:   CH3COOC2H5CH3C(O)OH + C2H4
Reaction order:   1
Temperature:   782 - 884 K
Pressure:  1.59E-3 - 2.55E-3 bar
Rate expression:   3.06x1012 [s-1] e-199547 [±417386 J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
782 1.44E-1
800 2.86E-1
825 7.11E-1
850 1.67E0
875 3.75E0
884 4.95E0