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Title: The kinetics of the pyrolysis of ethyl and isopropyl formates and acetates
Journal: Can. J. Chem.
Volume: 32
Page(s): 366 - 372
Year: 1954
Reference type: Journal article
Squib: 1954BLA366-372
Reaction:
CH3COOC2H5 → CH3C(O)OH + C2H4
Reaction order:
1
Temperature:
782 - 884
K
Pressure: 1.59E-3 - 2.55E-3 bar
Rate expression:
3.06x1012 [s-1] e-199547 [±417386 J/mole]/RT
Bath gas:
Toluene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 782 | 1.44E-1 |
| 800 | 2.86E-1 |
| 825 | 7.11E-1 |
| 850 | 1.67E0 |
| 875 | 3.75E0 |
| 884 | 4.95E0 |