Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Wijnen, M.H.J.
Title:   The reaction of methyl radicals with aceto- and propio-nitrile
Journal:   J. Chem. Phys.
Volume:   22
Page(s):  
Year:   1954
Reference type:   Journal article
Squib:   1954WIJ1074

Reaction:   CH3CN + CD3CHD3 + CH2CN
Reaction order:   2
Reference reaction:   (CD3)2CO + CD3 → Other Products + CD4
Reference reaction order:   2
Temperature:   373 - 563 K
Pressure:  6.00E-2 - 8.00E-2 bar
Rate expression:   1.08 e4132 [J/mole]/RT
Bath gas:   CH3CN
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
373 4.09E0
375 4.06E0
400 3.74E0
425 3.48E0
450 3.26E0
475 3.07E0
500 2.92E0
525 2.78E0
550 2.67E0
563 2.61E0