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Title: The study of chlorine atom reactions in the gas phase
Journal: J. Am. Chem. Soc.
Volume: 77
Page(s):
Year: 1955
Reference type: Journal article
Squib: 1955PRI/PYK2629
Reaction:
Cyclopentane + Cl → Cyclopentyl + HCl
Reaction order:
2
Reference reaction:
C2H6 + Cl → ·C2H5 + HCl
Temperature:
298 - 484
K
Pressure: 0.13 - 0.31 bar
Rate expression:
4.87x10-10 [cm3/molecule s] e-2420 [J/mole]/RT
Bath gas:
C2H6
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 1.83E-10 |
| 300 | 1.84E-10 |
| 325 | 1.99E-10 |
| 350 | 2.12E-10 |
| 375 | 2.24E-10 |
| 400 | 2.35E-10 |
| 425 | 2.45E-10 |
| 450 | 2.55E-10 |
| 475 | 2.64E-10 |
| 484 | 2.67E-10 |