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Title: The pyrolysis of p-xylene
Journal: J. Polym. Sci.
Volume: 15
Page(s): 203 - 219
Year: 1955
Reference type: Journal article
Squib: 1955SCH203-219
Reaction:
1,4-Dimethylbenzene → 4-Methylbenzyl + H·
Reaction order:
1
Temperature:
1070 - 1190
K
Pressure: 3.47E-3 - 1.63E-2 bar
Rate expression:
2.7x1014 [s-1] e-332579 [J/mole]/RT
Bath gas:
1,4-Dimethylbenzene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1070 | 1.57E-2 |
| 1075 | 1.87E-2 |
| 1100 | 4.35E-2 |
| 1125 | 9.77E-2 |
| 1150 | 2.12E-1 |
| 1175 | 4.43E-1 |
| 1190 | 6.81E-1 |