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Title: The oxidation of lower paraffin hydrocarbons. I. Room temperature reaction of methane, propane, n-butane and isobutane with ozonized oxygen
Journal: J. Am. Chem. Soc.
Volume: 78
Page(s): 2044 - 2048
Year: 1956
Reference type: Journal article
Squib: 1956SCH/PEA2044-2048
Reaction:
n-C4H10 + O3 → Products
Reaction order:
2
Temperature:
298 - 323
K
Pressure: 1.01 bar
Rate expression:
1.36x10-15 [cm3/molecule s] e-46395 [J/mole]/RT
Bath gas:
O3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 1.00E-23 |
| 300 | 1.14E-23 |
| 323 | 4.28E-23 |