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Author(s):   Birss, F.W.; Danby, C.J.; Hinshelwood, C.
Title:   The thermal dissociation of tertiary butyl peroxide in presence of nitric oxide
Journal:   Proc. R. Soc. London A
Volume:   239
Page(s):   154 - 164
Year:   1957
Reference type:   Journal article
Squib:   1957BIR/DAN154-164

Reaction:   (CH3)3CO· → (CH3)2CO + ·CH3
Reaction order:   1
Temperature:   403 - 443 K
Rate expression:   5.01x109 [s-1] e-55208 [±9977 J/mole]/RT
Bath gas:   (tert-C4H9O)2
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
403 3.50E2
425 8.22E2
443 1.55E3