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Title: The thermal dissociation of tertiary butyl peroxide in presence of nitric oxide
Journal: Proc. R. Soc. London A
Volume: 239
Page(s): 154 - 164
Year: 1957
Reference type: Journal article
Squib: 1957BIR/DAN154-164
Reaction:
(CH3)3CO → (CH3)2CO + ·CH3
Reaction order:
1
Temperature:
403 - 443
K
Rate expression:
5.01x109 [s-1] e-55208 [±9977 J/mole]/RT
Bath gas:
(tert-C4H9O)2
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 403 | 3.50E2 |
| 425 | 8.22E2 |
| 443 | 1.55E3 |