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Author(s):   Kraus, M.; Vavruska, M.; Bazant, V.
Title:   Diene durch pyrolyse von cyclischen verbindungen. III. Die kinetik der spaltung von cyclohexen und cyclohexylacetat
Journal:   Collect. Czech. Chem. Commun.
Volume:   22
Year:   1957
Reference type:   Journal article
Squib:   1957KRA/VAV484

Reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Reaction order:   1
Temperature:   937 - 1020 K
Pressure:  9.33E-3 - 9.33E-2 bar
Rate expression:   1.22x1012 [s-1] e-230311 [J/mole]/RT
Bath gas:   H2O
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
937 1.77E-1
950 2.65E-1
975 5.60E-1
1000 1.14E0
1020 1.96E0