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Title: The pyrolysis of cadmium dimethyl and dissociation energies of the cadmium-carbon bonds
Journal: Trans. Faraday Soc.
Volume: 53
Page(s): 1431 - 1436
Year: 1957
Reference type: Journal article
Squib: 1957LAU/LON1431-1436
Reaction:
(CH3)2Cd → ·CH3 + CH3Cd
Reaction order:
1
Temperature:
521 - 539
K
Pressure: 2.67E-2 bar
Rate expression:
1.15x1013 [s-1] e-182087 [±5463 J/mole]/RT
Bath gas:
(CH3)2Cd
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 521 | 6.39E-6 |
| 525 | 8.80E-6 |
| 539 | 2.60E-5 |