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Accessibility information
Author(s):   Reed, J.F.; Rabinovitch, B.S.
Title:   The sodium diffusion flame method for fast reactions. II. Reactions of fluorinated methyl chlorides
Journal:   J. Phys. Chem.
Volume:   61
Page(s):   598 - 605
Year:   1957
Reference type:   Journal article
Squib:   1957REE/RAB598-605

Reaction:   CHF2Cl + Na → ·CHF2 + NaCl
Reaction order:   2
Temperature:   580 - 590 K
Pressure:  3.33E-2 - 7.33E-2 bar
Rate expression:   7.47x10-15 [cm3/molecule s] e-41822 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
580 1.28E-18
590 1.48E-18