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Author(s):   Shilov, A.E.; Sabirova, R.D.
Title:   The mechanism and the isotope effect of the primary stage in the thermal breakdown of chloroform
Journal:   Dokl. Akad. Nauk SSR
Volume:   114
Page(s):   1058 - 1061
Year:   1957
Reference type:   Journal article
Squib:   1957SHI/SAB1058-1061

Reaction:   CHCl3CCl2 (X 1A1) + HCl
Reaction order:   1
Reference reaction:   CCl3D → CCl2 (X 1A1) + DCl
Reference reaction order:   1
Temperature:   847 K
Pressure:  1.57E-3 - 4.80E-2 bar
Rate expression:   1.65
Bath gas:   CHCl3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Other (direct)

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