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Title: Kinetics of the reaction of methyl radicals with toluene
Journal: J. Chem. Soc.
Page(s):
Year: 1958
Reference type: Journal article
Squib: 1958PRI/TRO4205
Reaction:
Toluene + ·CH3 → CH4 + Benzyl
Reaction order:
2
Reference reaction:
·CH3 + ·CH3 → C2H6
Temperature:
619 - 975
K
Pressure: 2.13E-2 bar
Rate expression:
1.38x10-11 [cm3/molecule s] e-54543 [±8314472 J/mole]/RT
Bath gas:
Toluene
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 619 | 3.45E-16 |
| 625 | 3.82E-16 |
| 650 | 5.72E-16 |
| 675 | 8.31E-16 |
| 700 | 1.18E-15 |
| 725 | 1.62E-15 |
| 750 | 2.20E-15 |
| 775 | 2.91E-15 |
| 800 | 3.79E-15 |
| 825 | 4.86E-15 |
| 850 | 6.15E-15 |
| 875 | 7.66E-15 |
| 900 | 9.44E-15 |
| 925 | 1.15E-14 |
| 950 | 1.39E-14 |
| 975 | 1.65E-14 |