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Accessibility information
Author(s):   Price, S.J.W.; Trotman-Dickenson, A.F.
Title:   Kinetics of the reaction of methyl radicals with toluene
Journal:   J. Chem. Soc.
Page(s):  
Year:   1958
Reference type:   Journal article
Squib:   1958PRI/TRO4205

Reaction:   Toluene + ·CH3CH4 + Benzyl
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   619 - 975 K
Pressure:  2.13E-2 bar
Rate expression:   1.38x10-11 [cm3/molecule s] e-54543 [±8314472 J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
619 3.45E-16
625 3.82E-16
650 5.72E-16
675 8.31E-16
700 1.18E-15
725 1.62E-15
750 2.20E-15
775 2.91E-15
800 3.79E-15
825 4.86E-15
850 6.15E-15
875 7.66E-15
900 9.44E-15
925 1.15E-14
950 1.39E-14
975 1.65E-14