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Accessibility information
Author(s):   Wijnen, M.H.J.
Title:   Photolysis of acetone in the presence of methyl-d3 acetate
Journal:   Can. J. Chem.
Volume:   36
Year:   1958
Reference type:   Journal article
Squib:   1958WIJ176

Reaction:   (CH3)2CO + ·CH3CH4 + CH3C(O)CH2(·)
Reaction order:   2
Reference reaction:   ·CH3 + CH3C(O)OCD3CH3D + CH3C(O)OCD2
Reference reaction order:   2
Temperature:   481 - 547 K
Pressure:  5.33E-2 - 0.17 bar
Rate expression:   2.35 e12555 [J/mole]/RT
Bath gas:   (CH3)2CO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
481 5.43E1
500 4.82E1
525 4.17E1
547 3.71E1