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Author(s):   Anson, P.C.; Fredricks, P.S.; Tedder, J.M.
Title:   Free-radical substitution in aliphatic compounds. Part I. Halogenation of n-Butane and isoButane in the gas phase
Journal:   J. Chem. Soc. A
Year:   1959
Reference type:   Journal article
Squib:   1959ANS/FRE918

Reaction:   n-C4H10 + ·Fsec-C4H9 + HF
Reaction order:   2
Reference reaction:   n-C4H10 + ·F1-C4H9 + HF
Reference reaction order:   2
Temperature:   298 - 459 K
Rate expression:   1.1 e399 [±83976 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 1.29E0
300 1.29E0
325 1.28E0
350 1.26E0
375 1.25E0
400 1.24E0
425 1.23E0
450 1.22E0
459 1.22E0