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Title: The hydrogenation of olefines. III. The disproportionation to combination ratios of the interaction of alkyl radicals
Journal: Proc. R. Soc. London A
Volume: 249
Page(s): 547 - 554
Year: 1959
Reference type: Journal article
Squib: 1959BOD/ROB547-554
Reaction:
iso-C3H7 + sec-C4H9 → n-C4H10 + CH3CH=CH2
Reaction order:
2
Reference reaction:
iso-C3H7 + sec-C4H9 → Pentane, 2,3-dimethyl-
Reference reaction order:
2
Temperature:
298
K
Pressure: 0.11 bar
Rate expression:
4.0x10-1
Bath gas:
Ar
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Sensitized photolysis
Analytical technique:
Mass spectrometry
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