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Title: The hydrogen isotope effect in the pyrolysis of ethyl-1,1,2,-d4 acetate
Journal: Can. J. Chem.
Volume: 38
Page(s): 1401 - 1406
Year: 1960
Reference type: Journal article
Squib: 1960BLA/GIL1401-1406
Reaction:
CH3C(O)OCD2CHD2 → CH3C(O)OH + C2D4
Reaction order:
1
Reference reaction:
CH3C(O)OCD2CHD2 → Acetic acid-d + CD2=CDH
Reference reaction order:
1
Temperature:
715 - 923
K
Rate expression:
9.91x10-1 e4789 [J/mole]/RT
Bath gas:
Toluene
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 715 | 2.22E0 |
| 725 | 2.19E0 |
| 750 | 2.14E0 |
| 775 | 2.08E0 |
| 800 | 2.04E0 |
| 825 | 1.99E0 |
| 850 | 1.95E0 |
| 875 | 1.91E0 |
| 900 | 1.88E0 |
| 923 | 1.85E0 |