Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Blades, A.T.; Gilderson, P.W.
Title:   The secondary hydrogen isotope effects in the pyrolysis of ethyl-d5 acetate and ethyl acetate-d3
Journal:   Can. J. Chem.
Volume:   38
Page(s):   1407 - 1411
Year:   1960
Reference type:   Journal article
Squib:   1960BLA/GIL1407-1411

Reaction:   CH3COOC2H5CH3C(O)OH + C2H4
Reaction order:   1
Temperature:   773 - 876 K
Rate expression:   3.86x1012 [s-1] e-201210 [±2012 J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
773 9.78E-2
775 1.06E-1
800 2.81E-1
825 7.04E-1
850 1.67E0
875 3.76E0
876 3.88E0