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Accessibility information
Author(s):   Blades, A.T.; Gilderson, P.W.
Title:   The secondary hydrogen isotope effects in the pyrolysis of ethyl-d5 acetate and ethyl acetate-d3
Journal:   Can. J. Chem.
Volume:   38
Page(s):   1407 - 1411
Year:   1960
Reference type:   Journal article
Squib:   1960BLA/GIL1407-1411

Reaction:   CH3COOC2H5CH3C(O)OH + C2H4
Reaction order:   1
Reference reaction:   CH3C(O)OC2D5C2D4 + Acetic acid-d
Reference reaction order:   1
Temperature:   660 - 763 K
Rate expression:   8.0x10-1 e6336 [±146335 J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
660 2.54E0
675 2.47E0
700 2.38E0
725 2.29E0
750 2.21E0
763 2.17E0