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Accessibility information
Author(s):   Blake, P.G.; Hinshelwood, C.
Title:   The homogeneous decomposition reactions of gaseous formic acid
Journal:   Proc. R. Soc. London A
Volume:   255
Page(s):   444 - 455
Year:   1960
Reference type:   Journal article
Squib:   1960BLA/HIN444-455

Reaction:   HCOOHCO2 + H2
Reaction order:   1
Temperature:   709 - 805 K
Pressure:  4.00E-3 - 0.87 bar
Rate expression:   6.31x104 [s-1] e-128043 [J/mole]/RT
Bath gas:   HCOOH
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
709 2.33E-5
725 3.76E-5
750 7.63E-5
775 1.48E-4
800 2.75E-4
805 3.10E-4