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Author(s):   Cvetanovic, R.J.; Doyle, L.C.
Title:   Reaction of oxygen atoms with butadiene
Journal:   Can. J. Chem.
Volume:   38
Page(s):   2187 - 2195
Year:   1960
Reference type:   Journal article
Squib:   1960CVE/DOY2187-2195

Reaction:   1,3-Butadiene + → Products
Reaction order:   2
Reference reaction:   Cyclopentene + → Products
Reference reaction order:   2
Temperature:   298 - 400 K
Pressure:  2.00E-2 - 6.40E-2 bar
Rate expression:   1.14 e-848 [J/mole]/RT
Bath gas:   1,3-Butadiene
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Sensitized photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 8.10E-1
300 8.11E-1
325 8.33E-1
350 8.52E-1
375 8.69E-1
400 8.83E-1