Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Hoare, D.E.; Wellington, C.A.
Title:   Reactions of t-butoxy, methoxy and acetonyl radicals
Journal:   Symp. Int. Combust. Proc.
Volume:   8
Page(s):  
Year:   1960
Reference type:   Journal article
Squib:   1960HOA/WEL472

Reaction:   CH2O + CH3CH3OH + HCO
Reaction order:   2
Reference reaction:   (CH3)2CO + CH3CH3OH + CH3C(O)CH2(·)
Reference reaction order:   2
Temperature:   393 - 473 K
Pressure:  1.27E-2 bar
Rate expression:   2.84 e16712 [J/mole]/RT
Bath gas:   (tert-C4H9O)2
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
393 4.73E2
400 4.32E2
425 3.22E2
450 2.47E2
473 1.99E2