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Accessibility information
Author(s):   Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   The reactions of alkyl radicals. Part III. n-Butyl radicals from the photolysis of n-Valeraldehyde
Journal:   J. Chem. Soc.
Page(s):  
Year:   1960
Reference type:   Journal article
Squib:   1960KER/TRO1602

Reaction:   n-C4H9 + n-C4H9n-C4H10 + 1-C4H8
Reaction order:   2
Reference reaction:   n-C4H9 + n-C4H9n-C8H18
Temperature:   334 - 502 K
Pressure:  1.60E-2 - 2.80E-2 bar
Rate expression:   6.61x10-10 [cm3/molecule s] e-5438 [J/mole]/RT
Bath gas:   n-C4H9CHO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
334 9.33E-11
350 1.02E-10
375 1.16E-10
400 1.29E-10
425 1.42E-10
450 1.55E-10
475 1.67E-10
500 1.79E-10
502 1.80E-10