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Title: The mechanism of the first stage in the thermal decomposition of chloromethanes. II. The decomposition of chloroform
Journal: Russ. J. Phys. Chem. (Engl. Transl.)
Volume: 34
Page(s): 408 - 411
Year: 1960
Reference type: Journal article
Squib: 1960SHI/SAB408-411
Reaction:
CHCl3 → CCl2 (X 1A1) + HCl
Reaction order:
1
Temperature:
783 - 857
K
Pressure: 1.73E-3 - 4.79E-2 bar
Rate expression:
2.61x1011 [s-1] e-197053 [J/mole]/RT
Bath gas:
CHCl3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 783 | 1.87E-2 |
| 800 | 3.55E-2 |
| 825 | 8.72E-2 |
| 850 | 2.03E-1 |
| 857 | 2.55E-1 |