NIST Chemical Kinetics Database

Author(s):   Avramenko, L.I.; Kolesnikova, R.V.; Kuznetsova, N.L.
Title:   Rate constant and mechanism of the reaction of atomic oxygen with methyl alcohol
Journal:   Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
Page(s):   552 - 555
Year:   1961
Reference type:   Journal article
Squib:   1961AVR/KOL552-555

Reaction:   CH₃OH + O· → Other Products + ·OH
Reaction order:   2
Temperature:   620 - 779 K
Pressure:  2.67E-3 - 1.87E-2 bar
Rate expression:   8.5x10^-13 [cm³/molecule s] e^{-12971 [±2070 J/mole]/RT}
Bath gas:   O2
Category: Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Other (direct)

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [cm³/molecule s]
620	6.87E-14
625	7.01E-14
650	7.71E-14
675	8.43E-14
700	9.16E-14
725	9.89E-14
750	1.06E-13
775	1.14E-13
779	1.15E-13