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Title: The reactions of methoxyl radicals with cyclopropane and isobutane
Journal: J. Chem. Soc.
Page(s):
Year: 1961
Reference type: Journal article
Squib: 1961BER/TRO348
Reaction:
C2H6 + CH3O· → CH3OH + ·C2H5
Reaction order:
2
Reference reaction:
Cyclopropane + CH3O· → CH3OH + Cyclopropyl
Reference reaction order:
2
Temperature:
468 - 597
K
Rate expression:
7.11x10-1 e11225 [±8314472 J/mole]/RT
Uncertainty:
1.3200001
Bath gas:
(CH3O)2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 468 | 1.27E1 |
| 475 | 1.22E1 |
| 500 | 1.06E1 |
| 525 | 9.30E0 |
| 550 | 8.28E0 |
| 575 | 7.44E0 |
| 597 | 6.82E0 |