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©NIST, 2013
Accessibility information
Author(s):   Errede, L.A.; DeMaria, F.
Title:   The chemistry of xylylenes. XV. The kinetics of fast flow pyrolysis of p-xylene
Journal:   J. Phys. Chem.
Volume:   66
Page(s):   2664 - 2672
Year:   1962
Reference type:   Journal article
Squib:   1962ERR/DEM2664-2672

Reaction:   1,4-DimethylbenzeneBenzyl + ·CH3
Reaction order:   1
Temperature:   1210 - 1380 K
Rate expression:   9.29x1012 [s-1] e300984 [J/mole]/RT
Bath gas:   1,4-Dimethylbenzene
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1210 9.14E25
1225 6.34E25
1250 3.51E25
1275 1.99E25
1300 1.15E25
1325 6.81E24
1350 4.11E24
1375 2.52E24
1380 2.29E24