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Title: The chemistry of xylylenes. XV. The kinetics of fast flow pyrolysis of p-xylene
Journal: J. Phys. Chem.
Volume: 66
Page(s): 2664 - 2672
Year: 1962
Reference type: Journal article
Squib: 1962ERR/DEM2664-2672
Reaction:
1,4-Dimethylbenzene → 4-Methylbenzyl + H·
Reaction order:
1
Temperature:
1210 - 1380
K
Rate expression:
9.29x1013 [s-1] e-317613 [J/mole]/RT
Bath gas:
1,4-Dimethylbenzene
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1210 | 1.81E0 |
| 1225 | 2.66E0 |
| 1250 | 4.97E0 |
| 1275 | 9.04E0 |
| 1300 | 1.61E1 |
| 1325 | 2.80E1 |
| 1350 | 4.78E1 |
| 1375 | 7.99E1 |
| 1380 | 8.84E1 |