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Accessibility information
Author(s):   Johnston, H.S.; Goldfinger, P.
Title:   Theoretical interpretation of reactions occurring in photochlorination
Journal:   J. Chem. Phys.
Volume:   37
Page(s):   700 - 709
Year:   1962
Reference type:   Journal article
Squib:   1962JOH/GOL700-709

Reaction:   ·CH2Cl + Cl2 → CH2Cl2 + Cl
Reaction order:   2
Temperature:   390 - 410 K
Rate expression:   6.61x10-12 [cm3/molecule s] e-18791 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
390 2.01E-14
400 2.32E-14
410 2.67E-14