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Title: Free radical substitution in aliphatic compounds. Part IV. The reaction of trichloromethyl radicals with propane, n-butane and iso-butane
Journal: Bull. Soc. Chim. Belg.
Volume: 71
Page(s):
Year: 1962
Reference type: Journal article
Squib: 1962MCG/TED772
Reaction:
iso-C4H10 + ·CCl3 → CHCl3 + tert-C4H9
Reaction order:
2
Reference reaction:
n-C4H10 + ·CCl3 → CHCl3 + sec-C4H9
Reference reaction order:
2
Temperature:
405 - 462
K
Pressure: 8.00E-2 bar
Rate expression:
5.6 e23031 [J/mole]/RT
Bath gas:
iso-C4H10
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 405 | 5.23E3 |
| 425 | 3.79E3 |
| 450 | 2.64E3 |
| 462 | 2.25E3 |