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Accessibility information
Author(s):   McGrath, B.P.; Tedder, J.M.
Title:   Free radical substitution in aliphatic compounds. Part IV. The reaction of trichloromethyl radicals with propane, n-butane and iso-butane
Journal:   Bull. Soc. Chim. Belg.
Volume:   71
Page(s):  
Year:   1962
Reference type:   Journal article
Squib:   1962MCG/TED772

Reaction:   iso-C4H10 + ·CCl3CHCl3 + tert-C4H9
Reaction order:   2
Reference reaction:   n-C4H10 + ·CCl3CHCl3 + sec-C4H9
Reference reaction order:   2
Temperature:   405 - 462 K
Pressure:  8.00E-2 bar
Rate expression:   5.6 e23031 [J/mole]/RT
Bath gas:   iso-C4H10
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
405 5.23E3
425 3.79E3
450 2.64E3
462 2.25E3