Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Substituent effects in pyrolysis. V. A p-σ+ correlation in the pyrolysis of 1-arylethyl acetates
Journal: J. Am. Chem. Soc.
Volume: 84
Page(s): 4817 - 4824
Year: 1962
Reference type: Journal article
Squib: 1962TAY/SMI4817-4824
Reaction:
Benzyl alcohol, p-iodo-α-methyl-, acetate → CH3C(O)OH + Benzene, 1-ethenyl-4-iodo-
Reaction order:
1
Temperature:
603 - 658
K
Pressure: 8.00E-3 - 0.27 bar
Rate expression:
6.98x1012 [s-1] e-184581 [J/mole]/RT
Bath gas:
Benzyl alcohol, p-iodo-α-methyl-, acetate
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 603 | 7.16E-4 |
| 625 | 2.62E-3 |
| 650 | 1.03E-2 |
| 658 | 1.55E-2 |