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Accessibility information
Author(s):   Thynne, J.C.J.; Gray, P.
Title:   The reactions of methoxyl radicals with methyl formate; comparisons between alkoxyl and alkyl
Journal:   Proc. Chem. Soc. London
Year:   1962
Reference type:   Journal article
Squib:   1962THY/GRA295

Reaction:   HC(O)OCH3 + CH3CH3OH + CH3OC(·)(O)
Reaction order:   2
Temperature:   393 - 458 K
Rate expression:   1.69x10-11 [cm3/molecule s] e-34256 [J/mole]/RT
Bath gas:   (CH3O)2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
393 4.74E-16
400 5.70E-16
425 1.04E-15
450 1.79E-15
458 2.10E-15