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Author(s):   Dixon, P.S.; Szwarc, M.
Title:   Reactions of CF3 radicals in the gaseous and liquid phases. Effect of solvent upon the rate constants
Journal:   Trans. Faraday Soc.
Volume:   59
Page(s):   112 - 117
Year:   1963
Reference type:   Journal article
Squib:   1963DIX/SZW112-117

Reaction:   1,3-Butadiene + ·CF3 → Adduct
Reaction order:   2
Reference reaction:   (CH3)2CHCH(CH3)2 + ·CF3CHF3 + (CH3)2CHC(·)(CH3)2
Reference reaction order:   2
Temperature:   338 K
Pressure:  0.47 bar
Rate expression:   7.82x102±1.6x101
Bath gas:   (CF3N)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.