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Accessibility information
Author(s):   Michel, K.W.; Olschewski, H.A.; Richtering, H.; Wagner, H.Gg.
Title:   Unterschung des thermischen Zerfalls von CO2
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   39
Page(s):   129 - 131
Year:   1963
Reference type:   Journal article
Squib:   1963MIC/OLS129-131

Reaction:   CO2CO +
Reaction order:   2
Temperature:   2850 - 4350 K
Pressure:  2.53 - 22.66 bar
Rate expression:   8.32x10-10 [cm3/molecule s] e-414061 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (IR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
2850 2.14E-17
2900 2.90E-17
3000 5.14E-17
3100 8.78E-17
3200 1.45E-16
3300 2.32E-16
3400 3.62E-16
3500 5.50E-16
3600 8.17E-16
3700 1.19E-15
3800 1.69E-15
3900 2.37E-15
4000 3.26E-15
4100 4.42E-15
4200 5.90E-15
4300 7.77E-15
4350 8.87E-15