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Home ©NIST, 2013 Accessibility information |
Title: Gas phase pyrolysis of alkyl acetates
Journal: Recueil
Volume: 82
Page(s): 1123 - 1154
Year: 1963
Reference type: Journal article
Squib: 1963SCH/KOO1123-1154
Reaction:
CH3COOC2H5 → CH3C(O)OH + C2H4
Reaction order:
1
Temperature:
725 - 810
K
Rate expression:
4.94x1011 [s-1] (T/298 K)1.00 e-194559 [±1946 J/mole]/RT
Bath gas:
CH3COOC2H5
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 725 | 1.16E-2 |
| 750 | 3.50E-2 |
| 775 | 9.91E-2 |
| 800 | 2.63E-1 |
| 810 | 3.82E-1 |