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Title: The unimolecular isomerization of methyl-d3 isocyanide. Statistical-weight inverse secondary intermolecular kinetic isotope effects in nonequilibrium thermal systems
Journal: J. Am. Chem. Soc.
Volume: 85
Page(s): 2365 - 2370
Year: 1963
Reference type: Journal article
Squib: 1963SCH/RAB2365-2370
Reaction:
CH3NC → CH3CN
Reaction order:
1
Reference reaction:
CD3NC → CD3CN
Reference reaction order:
1
Temperature:
453 - 523
K
Pressure: 10.13 bar
Rate expression:
9.2x10-1 e399 [±167121 J/mole]/RT
Bath gas:
CD3NC
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 453 | 1.02E0 |
| 475 | 1.02E0 |
| 500 | 1.01E0 |
| 523 | 1.01E0 |