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Author(s):   Thynne, J.C.J.; Gray, P.
Title:   Methoxyl-radical-induced decomposition of methyl formate: Kinetics of methoxyl and methyl radical reactions
Journal:   Trans. Faraday Soc.
Volume:   59
Year:   1963
Reference type:   Journal article
Squib:   1963THY/GRA1149

Reaction:   HC(O)OCH3 + CH3CH3OH + CH3OC(·)(O)
Reaction order:   2
Temperature:   393 - 455 K
Pressure:  1.73E-2 - 1.00E-1 bar
Rate expression:   2.69x10-12 [cm3/molecule s] e-34256 [±8314472 J/mole]/RT
Uncertainty:   1.74
Bath gas:   He
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
393 7.53E-17
400 9.05E-17
425 1.66E-16
450 2.84E-16
455 3.14E-16