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Title: Kinetics of the effects of nitric oxide and nitrosyl chloride on the gas-phase chlorination of chloroform
Journal: Trans. Faraday Soc.
Volume: 60
Page(s):
Year: 1964
Reference type: Journal article
Squib: 1964ASH/SPE1608
Reaction:
CHCl3 + Cl → ·CCl3 + HCl
Reaction order:
2
Temperature:
470 - 575
K
Pressure: 0.13 bar
Rate expression:
3.55x10-12 [cm3/molecule s] e-9063 [J/mole]/RT
Bath gas:
CHCl3
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 470 | 3.50E-13 |
| 475 | 3.58E-13 |
| 500 | 4.02E-13 |
| 525 | 4.46E-13 |
| 550 | 4.90E-13 |
| 575 | 5.34E-13 |